Organic solvents

Organic solvents are substances or mixtures used to dissolve other materials in processes such as cleaning, painting, printing, or manufacturing. Their prevention depends on their composition and conditions of use, not just their brand name.

In short

Solvents can cause exposure through inhalation and skin contact, and in many cases, pose a fire risk. Substitution, emissions control, and proper work practices are priority measures.

Content
  1. What are they and where are they used?
  2. Composition and specific hazards
  3. Exposure routes and relevant tasks
  4. Effects and risk of accident
  5. Replacement and emissions control
  6. Practical example
  7. Evaluation and monitoring
  8. Common mistakes
  9. Related concepts
  10. On the blog
  11. References

AZ Dictionary →

What are they and where are they used?

A solvent allows materials to be dissolved or dispersed in a given application. Organic solvents are found in cleaners, adhesives, inks, coatings, and other industrial products. They can be used as a single substance or as a mixture, with trade names that do not, by themselves, explain their composition or hazards.

Their presence is not limited to the chemical industry. A workshop, a printing press, or a maintenance service can use them in small quantities and generate relevant exposures if the task releases vapors or involves skin contact. The assessment should identify the specific product and observe how it is opened, applied, removed, and stored.

Composition and specific hazards

Not all solvents have the same toxicity, volatility, or flammability. Some families and substances present different hazards, so it is incorrect to attribute all the effects described for the entire group to any single solvent. The safety data sheet and the current classification allow you to specify which aspects require evaluation.

In a mixture, the proportion and interaction of its components are also important. A change in supplier or formulation can alter exposure even if the commercial use remains the same. Purchasing and safety managers must have sufficient information to assess this change before considering the new product equivalent to the previous one.

Exposure routes and relevant tasks

Evaporation can release contaminants into the air in the breathing zone. The amount released depends on the product and conditions such as the exposed surface, temperature, and application method. Spraying, manual cleaning, or leaving impregnated cloths on surfaces creates different scenarios than keeping a container properly sealed.

Dermal exposure requires special attention: hands, forearms, and clothing can come into contact with contaminated liquids or surfaces. Routes of entry also include accidental ingestion through contamination of hands and objects. The study should encompass maintenance and waste management, where exposures may occur that are not present during the automated process.

Effects and risk of accident

Depending on the substance and exposure, irritation and effects on the nervous system or other organs may occur. Some substances present specific hazards of greater severity. Health assessment and surveillance must be based on the agents actually present; a general information sheet does not allow for attributing individual symptoms to a specific cause.

Many solvents are flammable, and their vapors can contribute to hazardous atmospheres. Ignition sources, transfer operations, and storage conditions must be evaluated. An acceptable concentration from a specific perspective does not automatically replace the assessment of all other hazards. Control must integrate hygiene, process safety, and workplace characteristics.

Replacement and emissions control

The substitution may involve changing the product or eliminating the need for it through another process. The alternative must be evaluated holistically: toxicity, effectiveness, required temperature, residues, and potential new hazards. A water-based product or one with less odor cannot be considered safe without reviewing its information.

When exposure persists, closed systems, proper dosing, and source capture are prioritized. Open quantities are limited, cloths and waste are managed, and equipment cleaning procedures are defined. Ventilation must be checked in the actual working position, preventing the contaminant from passing through the breathing zone before being captured.

Practical example

A printing company manually cleans parts using an open container and several cloths. The assessment identifies evaporation during breaks and hand contact when retrieving the cloths. An alternative cleaning method is studied and its effectiveness, as well as its hazards, is tested with the participation of those performing the task.

The selected solution incorporates a controlled application system, waste collection, and capture where applicable. Protection is defined for residual risk, and its removal is carried out. Verification includes a representative workday and final cleaning. This avoids carrying out the main application while exposure remains present during auxiliary operations.

Evaluation and monitoring

The assessment of inhalation exposure should use methods appropriate to the components and current criteria. Daily and short-term exposure values ​​require different reference periods. The measurement should represent tasks, times, and conditions, and consider mixtures according to the applicable method.

Monitoring combines control checks, change reviews, and incident logging. A hood that is installed but misused or a container left open can skew the assessed scenario. Training needs to explain how the control measure works and what signs of deterioration should be reported, along with a procedure for taking action without improvisation.

Common mistakes

Common mistakes include using smell as a gauge, cleaning skin with solvent, choosing gloves solely based on appearance, and assuming that small quantities pose no risk. Other errors include keeping unlabeled secondary containers or mixing waste for convenience without checking compatibility.

Effective management keeps inventory, technical information, and instructions aligned with actual work practices. When a substance changes or a new task arises, the safety assessment is reviewed before its widespread use. The goal is to reduce exposure and prevent accidents, not simply to store safety data sheets that no one consults at the workstation.

Related concepts

On the blog

References

  1. Official State Gazette. Royal Decree 374/2001, on protection against chemical agents at work. Consolidated text. Official source
  2. National Institute for Occupational Safety and Health. Solvents and health: risks and prevention. 2001. Informative reference. Official source
  3. National Institute for Occupational Safety and Health. Occupational exposure limits for chemical agents in Spain. 2026 Edition. Official Source

Editorial information

Publication date: October 10, 2026.

Editorial Manager: Sabentis Editorial Team.

Author: Pablo Rodríguez LinkedIn

Executive Vice President of the ORP International Foundation and Chief Financial Officer of Sabentis.

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