UNE-EN 689 and inhalation exposure

UNE-EN 689 describes a strategy for obtaining representative inhalation exposure measurements and assessing their compliance with limit values. Its application requires knowledge of the work, designing the sampling, and interpreting the variability.

In short

Applying UNE-EN 689 involves following a comprehensive strategy, from characterizing the exposure to making a decision and reviewing it. A single sample below the limit does not automatically equate to compliance.

Content
  1. What does this standard contribute?
  2. Relationship with preventive obligations
  3. Characterize before measuring
  4. Groups and measurement design
  5. Decision and variability
  6. Practical example
  7. Review and follow-up
  8. What should the report allow you to verify?
  9. Related concepts
  10. On the blog
  11. References

AZ Dictionary →

What does this standard contribute?

UNE-EN 689 is a technical standard for assessing inhalation exposure to chemical agents against exposure limits. It addresses a practical problem: exposure varies between tasks, individuals, and workdays, while available measurements are necessarily limited. Therefore, the conclusion requires a representative strategy and appropriate decision criteria.

The INSST cites the 2019 edition in its sampling and analysis forms. For its application, the complete standard and any corresponding corrections or updates must be consulted. This form explains its purpose and its preventive integration; it does not reproduce the tables, tests, or detailed requirements necessary to perform an assessment in accordance with the standard.

Relationship with preventive obligations

In Spain, Royal Decree 374/2001 regulates the assessment and prevention of risks from chemical agents. It includes measurements to assess inhalation exposure and requires justification for situations where the nature and extent of the risk allow for sufficient assessment by other means. The decision must be based on evidence, not merely on the absence of complaints.

A technical standard helps develop the evaluation, but it does not replace legal obligations or competent professional judgment. Nor does it transform any report that cites it into a compliant study. There must be consistency between the stated methodology, the fieldwork, the analytical information, and the conclusion reached.

Characterize before measuring

The characterization describes the agents present, the emission sources, the tasks, the exposed personnel, and the existing safeguards. It should include foreseeable non-routine operations and changes in conditions. Historical data can provide information, provided it is verified that it accurately reflects the current process and that its quality is sufficient for the intended use.

This phase allows for defining specific questions: what exposure is being assessed, what scenarios might differ, and what information is missing. Measuring first and then reconstructing the context can lead to results that are difficult to interpret. Visiting the workplace and speaking with those performing the work are necessary to identify tasks not included in the formal job description.

Groups and measurement design

Similar exposure groups allow for the organization of individuals with comparable profiles for the agent being evaluated. Their formation must be justified by working conditions. Simply grouping those who share the same job title or belong to the same department is insufficient. The grouping is reviewed if observations or results reveal significant differences.

The measurement plan defines the people, days, tasks, duration, and procedures. The choice between personal or fixed-point sampling should be based on the objective and the method. Field records and incidents that could affect validity are also anticipated. These details allow us to understand which population and conditions the data represent.

Decision and variability

The comparison must use the correct reference value and respect its period: VLA-ED or VLA-EC, as applicable. The assessment considers variability and applies the criteria established by the procedure. A low average or a selection of favorable results is not sufficient to declare the conformity of the set.

When the information does not allow for a sufficient conclusion, the report must acknowledge this and define how to resolve it. When there is evidence of inadequate exposure, the priority is to control the risk. Data collection should not be prolonged indefinitely to avoid a preventive decision, nor should a valid measurement be discarded because it worsens the outcome.

Practical example

A company has a sample result below the exposure limit, obtained during a low-production day. They intend to use this sample to finalize the evaluation of all personnel on a production line. Upon reviewing the data, the technician discovers that cleaning was not included, different formulations are being used, and some team members work a different shift.

Each situation is characterized and the sampling plan is reviewed. Obvious control measures are addressed without waiting for all the data to be collected. The final report links each conclusion to the scenario it represents and establishes the conditions that will require its revision. The improvement lies in making the decision defensible, not simply in increasing the number of samples.

Review and follow-up

An assessment describes specific working conditions. Changes in product, process, activity level, ventilation, or tasks can cause it to no longer accurately reflect those conditions. Monitoring should detect these changes and trigger a review, in addition to the periodic checks determined by the procedure and the situation being assessed.

The company needs a mechanism to inform the occupational health and safety service before making any significant changes. It must also verify that the existing measures are still effective: maintenance of the intake system, closure of containers, availability of equipment, and adherence to the established work procedures. The absence of new measurements does not demonstrate that conditions have remained stable.

What should the report allow you to verify?

The report must identify the agent and the comparison criterion, explain the scenarios and groups, describe the strategy, and present the results along with the conditions under which they were obtained. It must also include details of the findings, limitations, and justification for the conclusion. Anyone reviewing the study should be able to follow the reasoning from the task to the preventive measure.

The most frequent errors are citing the standard without applying it, using administrative groupings, measuring only convenient moments, and confusing compliance with the absence of any chemical risk. The inhalation strategy does not replace the assessment of skin contact, accidents, or hazardous reactions. A comprehensive assessment integrates these issues with methods and measures appropriate to each.

Related concepts

On the blog

References

  1. Official State Gazette. Royal Decree 374/2001, on protection against chemical agents at work. Consolidated text. Official source
  2. Official State Gazette. Royal Decree 39/1997, Regulations for Prevention Services. Consolidated text. Official source
  3. Spanish Association for Standardization. Workplace exposure: measurement of inhalation exposure to chemical agents. Official source
  4. National Institute for Occupational Safety and Health. Technical guide for the assessment and prevention of risks related to chemical agents. 2022. Official source
  5. National Institute for Occupational Safety and Health. Sampling and Analysis Forms for Chemical Agents. 2025. Official Source

Editorial information

Publication date: October 10, 2026.

Editorial Manager: Sabentis Editorial Team.

Author: Pablo Rodríguez LinkedIn

Executive Vice President of the ORP International Foundation and Chief Financial Officer of Sabentis.

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